Anion Gap + Delta-Delta Ratio

Figge albumin-corrected AG with mixed acid-base interpretation
Calculates the raw and albumin-corrected anion gap using the Figge correction, then computes the delta ratio to identify mixed acid-base disorders hidden behind a high-AG metabolic acidosis.
Acid-Base Nephrology Critical Care ICU
Enter Values
Albumin-Corrected Anion Gap (mEq/L)
Enter values to calculate
Normal = 4.0 g/dL. Required for Figge correction.

Formulas

Raw Anion Gap
AG = Na−(Cl + HCO₃)
Figge Albumin Correction
Corrected AG = AG + 2.5 × (4.0 − Albumin)
Delta Ratio
Δ/Δ = (AG − 12) / (24 − HCO₃)

The normal anion gap is 8–12 mEq/L (with albumin at 4 g/dL). For every 1 g/dL fall in albumin below 4 g/dL, the expected AG falls by approximately 2.5 mEq/L — making hypoalbuminaemia the commonest cause of a spuriously normal AG.

Delta Ratio Interpretation

Delta RatioInterpretation
<0.4Normal AG acidosis / hyperchloraemic metabolic acidosis
0.4–0.9Mixed high-AG + normal-AG metabolic acidosis
1.0–2.0Pure high-AG metabolic acidosis (expected)
>2.0High-AG acidosis + concurrent metabolic alkalosis

The delta ratio is only meaningful when the corrected AG is elevated (>12 mEq/L). It compares the rise in AG above normal against the fall in bicarbonate below normal to identify co-existing disorders.

MUDPILES — Causes of High-AG Metabolic Acidosis

  • M — Methanol
  • U — Uraemia (renal failure)
  • D — Diabetic ketoacidosis (DKA)
  • P — Propylene glycol / Paraldehyde
  • I — Iron, Isoniazid, Inborn errors of metabolism
  • L — Lactic acidosis (type A and B)
  • E — Ethylene glycol
  • S — Salicylates (aspirin overdose)

Clinical Application

When to correct for albumin: Always use the Figge correction in critically ill patients, those with liver disease, nephrotic syndrome, or malnutrition — all conditions where hypoalbuminaemia is prevalent. A "normal" raw AG in a hypoalbuminaemic patient may conceal a significant unmeasured anion load.

Approach to mixed acid-base disorders: Once an elevated corrected AG is confirmed, apply the delta ratio. A ratio <1 suggests a concomitant normal-AG acidosis (e.g., diarrhoea + DKA). A ratio >2 suggests a concurrent metabolic alkalosis (e.g., vomiting + DKA, or diuretic use).

Limitations: The delta ratio assumes a baseline AG of 12 and baseline HCO₃ of 24. Chronic respiratory compensation will alter HCO₃; adjust interpretation accordingly. The ratio is unreliable in pure lactic acidosis where lactate is rapidly cleared.

References

  1. Figge J, Mydosh T, Fencl V. Serum proteins and acid-base equilibria: a follow-up. J Lab Clin Med. 1992;120(5):713–719.
  2. Winter SD, Pearce JL, Gabow PA. The fall of serum anion gap. Ann Intern Med. 1990;108(2):185–188.
  3. Emmett M, Narins RG. Clinical use of the anion gap. Medicine (Baltimore). 1977;56(1):38–54.
  4. Oh MS, Carroll HJ. The anion gap. N Engl J Med. 1977;297(15):814–817.

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